Chiral phosphines in nucleophilic organocatalysis

This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita-Baylis-Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines,...

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Veröffentlicht in:	Beilstein journal of organic chemistry 2014-09, Vol.10 (1), p.2089-2121
Hauptverfasser:	Xiao, Yumei, Sun, Zhanhu, Guo, Hongchao, Kwon, Ohyun
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric catalysis Chemistry chiral phosphine nucleophilic organocatalysis organophosphorus Review synthesis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita-Baylis-Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols.
ISSN:	1860-5397 1860-5397
DOI:	10.3762/bjoc.10.218