Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes

Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as CPBA are employed to in situ generate iodine(III) species. In this r...

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Veröffentlicht in:Beilstein journal of organic chemistry 2018-07, Vol.14 (1), p.1813-1825
Hauptverfasser: Li, Xiang, Chen, Pinhong, Liu, Guosheng
Format: Artikel
Sprache:eng
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Zusammenfassung:Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as CPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized.
ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.14.154