catena-Poly[calcium-bis-[μ-N-(dimethyl-phosphino-yl)benzene-sulfonamidato]]

The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O-S-O-Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging...

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Veröffentlicht in:	Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-09, Vol.65 (Pt 10), p.m1231-m1231
Hauptverfasser:	Trush, Elizaveta A, Trush, Victor A, Sliva, Tetyana Yu, Konovalova, Irina S, Amirkhanov, Volodymyr M
Format:	Artikel
Sprache:	eng
Schlagworte:	Metal-Organic Papers
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O-S-O-Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octa-hedral geometry.
ISSN:	1600-5368 1600-5368
DOI:	10.1107/S1600536809032875