3D Architectured Graphene/Metal Oxide Hybrids for Gas Sensors: A Review

Graphene/metal oxide-based materials have been demonstrated as promising candidates for gas sensing applications due to the enhanced sensing performance and synergetic effects of the two components. Plenty of metal oxides such as SnO₂, ZnO, WO₃, etc. have been hybridized with graphene to improve the gas sensing properties. However, graphene/metal oxide nanohybrid- based gas sensors still have several limitations in practical application such as the insufficient sensitivity and response rate, and long recovery time in some cases. To achieve higher sensing performances of graphene/metal oxides nanocomposites, many recent efforts have been devoted to the controllable synthesis of 3D graphene/metal oxides architectures owing to their large surface area and well-organized structure for the enhanced gas adsorption/diffusion on sensing films. This review summarizes recent advances in the synthesis, assembly, and applications of 3D architectured graphene/metal oxide hybrids for gas sensing.