Breathing some new life into an old topic: chalcogen-nitrogen π-heterocycles as electron acceptors

Breathing some new life into an old topic: chalcogen-nitrogen π-heterocycles as electron acceptors

Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer comp...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2013-08, Vol.18 (8), p.9850-9900
Hauptverfasser: Lonchakov, Anton V, Rakitin, Oleg A, Gritsan, Nina P, Zibarev, Andrey V
Format: Artikel
Sprache:eng
Schlagworte:
Chalcogens - chemistry
charge-transfer complexes
Electron Transport
Nitrogen - chemistry
organic electron acceptors
radical-anion salts
Review
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Zusammenfassung:Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts-candidate building blocks of molecule-based electrical and magnetic functional materials.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules18089850