catena-Poly[[bis-[1-(2-hydroxy-ethyl)-1H-tetra-zole-κN]copper(II)]-di-μ-chlorido]: a powder study

The crystal structure of the title polymeric complex, [CuCl(2)(C(3)H(6)N(4)O)(2)](n), was obtained by the Rietveld refinement from laboratory X-ray powder diffraction data collected at room temperature. The unique Cu(II) ion lies on an inversion center and is in a slightly distorted octa-hedral coor...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-07, Vol.64 (Pt 8), p.m1044-m1045
Hauptverfasser: Ivashkevich, Ludmila S, Lyakhov, Alexander S, Serebryanskaya, Tatiyana V, Gaponik, Pavel N
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Sprache:eng
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Zusammenfassung:The crystal structure of the title polymeric complex, [CuCl(2)(C(3)H(6)N(4)O)(2)](n), was obtained by the Rietveld refinement from laboratory X-ray powder diffraction data collected at room temperature. The unique Cu(II) ion lies on an inversion center and is in a slightly distorted octa-hedral coordination environment. In the hydroxy-ethyl group, all H atoms, the O atom and its attached C atom are disordered over two positions; the site occupancy factors are ca 0.6 and 0.4. The OH group is involved in an intra-molecular O-H⋯N hydrogen bond.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808022137