Bis(ethanamidinium) (1,10-phenanthroline-2,9-dicarboxylato)manganate(II) heptahydrate
In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the MnII atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional s...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-01, Vol.69 (1), p.m10-m11 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the MnII atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supramolecular structure is formed through N-H...O and O-H...O hydrogen bonds and π-π stacking interactions [centroid-centroid distance = 3.553 (2) Å]. |
|---|---|
| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536812048350 |