In Situ Electric‐Induced Switchable Transparency and Wettability on Laser‐Ablated Bioinspired Paraffin‐Impregnated Slippery Surfaces

Switchable wetting and optical properties on a surface is synergistically realized by mechanical or temperature stimulus. Unfortunately, in situ controllable wettability together with programmable transparency on 2D/3D surfaces is rarely explored. Herein, Joule‐heat‐responsive paraffin‐impregnated slippery surface (JR‐PISS) is reported by the incorporation of lubricant paraffin, superhydrophobic micropillar‐arrayed elastomeric membrane, and embedded transparent silver nanowire thin‐film heater. Owing to its good flexibility, in situ controllable locomotion for diverse liquids on planar/curved JR‐PISS is unfolded by alternately applying/discharging low electric‐trigger of 6 V. Simultaneously, optical visibility can be reversibly converted between opaque and transparent modes. The switching principle is that in the presence of Joule‐heat, solid paraffin would be melt and swell within 20 s to enable a slippery surface for decreasing light scattering and frictional force derived from contact angle hysteresis (FCAH). Once Joule‐heat is discharged, undulating rough surface would reconfigure by cold‐shrinkage of paraffin within 8 s to render light blockage and high FCAH. Upon its portable merit, in situ thermal management, programmable visibility, as well as steering functionalized droplets by electric‐activated JR‐PISSs are successfully deployed. Compared with previous Nepenthes‐inspired slippery surfaces, the current JR‐PISS is more competent for in situ harnessing optical and wetting properties on‐demand. Switchable optical and wetting properties are highly desirable for up‐to‐date smart surfaces. By embedding a portable, low‐voltage‐driven and transparent silver nanowires heater, the sandwich‐structured bioinspired Joule‐heat‐responsive paraffin‐impregnated slippery surface (JR‐PISS) is competent for in situ tuning these two features in synergy. Insights into the rational design of electric‐induced actuator offer a platform for developing and optimizing next‐generation smart windows.