PVC-Based Cerium Phosphate Membrane Exhibiting Selectivity for Molybdate Anions

A PVC-based membrane containing cerium phosphate was developed. Unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. Therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. The response...

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Veröffentlicht in:Iranian journal of chemistry & chemical engineering 2000-01, Vol.19 (2), p.51-55
Hauptverfasser: Hassan Khodakarami, Hedayat O. Ghourchian
Format: Artikel
Sprache:eng
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Zusammenfassung:A PVC-based membrane containing cerium phosphate was developed. Unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. Therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. The response of molybdate selective electrode based on this membrane was perfectly linear in the concentration range 1.98´10-5 to 10-1 M. Characteristics of this electrode such as electric resistance, stability and membrane preconditioning process, and regeneration of its sensitivity are reported.
ISSN:1021-9986
1021-9986