N,N #8242;-Bis(4-chlorobenzylidene)-3,3 #8242;-dimethoxybiphenyl-4,4 #8242;-diamine

The title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for molec...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-06, Vol.67 (6), p.o1296-o1297
Hauptverfasser: Ashokkumar Subashini, Kandasamy Ramamurthi, Helen Stoeckli-Evans
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for molecules A and B, respectively. In the crystal, A molecules are related as centrosymmetric pairs through a weak π–π interaction [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of intermolecular C—H...O, C—H...N and C—H...π interactions present.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811015467