Hierarchically Structured Porous Piezoelectric Polymer Nanofibers for Energy Harvesting

Hierarchically porous piezoelectric polymer nanofibers are prepared through precise control over the thermodynamics and kinetics of liquid–liquid phase separation of nonsolvent (water) in poly(vinylidene fluoride‐trifluoroethylene) (P(VDF‐TrFE)) solution. Hierarchy is achieved by fabricating fibers with pores only on the surface of the fiber, or pores only inside the fiber with a closed surface, or pores that are homogeneously distributed in both the volume and surface of the nanofiber. For the fabrication of hierarchically porous nanofibers, guidelines are formulated. A detailed experimental and simulation study of the influence of different porosities on the electrical output of piezoelectric nanogenerators is presented. It is shown that bulk porosity significantly increases the power output of the comprising nanogenerator, whereas surface porosity deteriorates electrical performance. Finite element method simulations attribute the better performance to increased volumetric strain in bulk porous nanofibers. This work links the thermodynamics of the polymer/solvent/nonsolvent ternary system, to the hierarchically engineered porous structure in polymer nanofibers. The model is experimentally substantiated with piezoelectric polymer fibers, where it is shown that due to the porosity, the electrical output of comprising piezoelectric nanogenerators is significantly improved, which, though finite element simulations, is attributed to the increased volumetric strain in bulk porous nanofibers.