1-(4-Nitrobenzoyl)-3-(4-nitrophenyl)thiourea acetone hemisolvate

In the title compound, C14H10N4O5S·0.5C3H6O, the nitrobenzoyl and nitrophenyl groups have trans and cis configurations, respectively, with respect to the thiourea S atom. The molecular conformation is stabilized by intramolecular N-H...O and C-H...S hydrogen bonds. The acetone solvent molecule posse...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-11, Vol.64 (11), p.o2138-o2138
Hauptverfasser: Xian, Liang, Cui, Lujuan, Cheng, Ming
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C14H10N4O5S·0.5C3H6O, the nitrobenzoyl and nitrophenyl groups have trans and cis configurations, respectively, with respect to the thiourea S atom. The molecular conformation is stabilized by intramolecular N-H...O and C-H...S hydrogen bonds. The acetone solvent molecule possesses a crystallographically imposed twofold axis. In the crystal packing, thiourea molecules are linked by intermolecular C-H...O hydrogen-bond interactions to form chains running parallel to the c axis. The chains are further bridged via N-H...O and C-H...O hydrogen bonds involving the acetone molecules.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680803359X