1-(4-Nitrobenzoyl)-3-(4-nitrophenyl)thiourea acetone hemisolvate
In the title compound, C14H10N4O5S·0.5C3H6O, the nitrobenzoyl and nitrophenyl groups have trans and cis configurations, respectively, with respect to the thiourea S atom. The molecular conformation is stabilized by intramolecular N-H...O and C-H...S hydrogen bonds. The acetone solvent molecule posse...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-11, Vol.64 (11), p.o2138-o2138 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, C14H10N4O5S·0.5C3H6O, the nitrobenzoyl and nitrophenyl groups have trans and cis configurations, respectively, with respect to the thiourea S atom. The molecular conformation is stabilized by intramolecular N-H...O and C-H...S hydrogen bonds. The acetone solvent molecule possesses a crystallographically imposed twofold axis. In the crystal packing, thiourea molecules are linked by intermolecular C-H...O hydrogen-bond interactions to form chains running parallel to the c axis. The chains are further bridged via N-H...O and C-H...O hydrogen bonds involving the acetone molecules. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S160053680803359X |