Bifunctional dendrons for multiple carbohydrate presentation via carbonyl chemistry

Bifunctional dendrons for multiple carbohydrate presentation via carbonyl chemistry

The synthesis of new dendrons of the generations 0, 1 and 2 with a double bond at the focal point and a carbonyl group at the termini has been carried out. The carbonyl group has been exploited for the multivalent conjugation to a sample saccharide by reductive amination and alkoxyamine conjugation.

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Veröffentlicht in:Beilstein journal of organic chemistry 2014-07, Vol.10 (1), p.1686-1691
Hauptverfasser: Bini, Davide, Nicotra, Francesco, Cipolla, Laura
Format: Artikel
Sprache:eng
Schlagworte:
bis-MPA
carbohydrates
Chemistry
dendrons
Letter
levulinic acid
multivalency
multivalent glycosystems
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Zusammenfassung:The synthesis of new dendrons of the generations 0, 1 and 2 with a double bond at the focal point and a carbonyl group at the termini has been carried out. The carbonyl group has been exploited for the multivalent conjugation to a sample saccharide by reductive amination and alkoxyamine conjugation.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.10.177