H₂S Sensing by Hybrids Based on Nanocrystalline SnO₂ Functionalized with Cu(II) Organometallic Complexes: The Role of the Ligand Platform

This paper deals with the functionalization of nanocrystalline SnO₂ with Cu(II) complexes with organic ligands, aimed at the improvement of sensor selectivity towards gas molecules. For the synthesis of metalorganic/SnO₂ hybrid material complexes of Cu(II) with phthalocyanine, porphyrinines, bipyridine and azadithiacrown etherwere used. The analysis of gas sensor properties showed the possibility of increasing the sensitivity and selectivity of hybrid materials in H₂S detection due to the electron transfer from SnO₂ to an adsorbed organic molecule, which changes during the interaction between H₂S and Cu(II) ions.