Di- #956;-iodido-bis[acetyl(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)(N-nitroso-N-oxidoaniline- #954;2O,O #8242;)rhodium(III)]

Di- #956;-iodido-bis[acetyl(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)(N-nitroso-N-oxidoaniline- #954;2O,O #8242;)rhodium(III)]

The title compound, [Rh2(C6H5N2O2)2(C2H3O)2I2(C5H9O3P)2], contains a binuclear centrosymmetric RhIII dimer bridged by iodide anions, with respective Rh...Rh and I...I distances of 4.1437 (5) and 3.9144 (5) Å. The RhIII atom is in a distorted octahedral RhCI2O2P...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-12, Vol.65 (12), p.m1528-m1529
Hauptverfasser: H. G. Visser, W. Purcell, Johan A. Venter
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, [Rh2(C6H5N2O2)2(C2H3O)2I2(C5H9O3P)2], contains a binuclear centrosymmetric RhIII dimer bridged by iodide anions, with respective Rh...Rh and I...I distances of 4.1437 (5) and 3.9144 (5) Å. The RhIII atom is in a distorted octahedral RhCI2O2P coordination with considerably different Rh—I distances to the bridging iodide anions. There are no classical hydrogen-bonding interactions observed for this complex.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809043050