( Z )-3-(4-Chlorophenyl)-2-(2-phenylcyclohex-2-en-1-ylimino)thiazolidin-4-one

The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclohexene ring adopts a distorted half-chair conformation. The thiazolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) an...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-07, Vol.68 (7), p.o1999-o2000
Hauptverfasser: Ooi, Chin Wei, Fun, Hoong-Kun, Quah, Ching Kheng, Sathishkumar, Murugan, Ponnuswamy, Alagusundaram
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclohexene ring adopts a distorted half-chair conformation. The thiazolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) and makes dihedral angles of 62.92 (6) and 56.32 (6)°, respectively, with the benzene ring and the chloro-substituted benzene ring. The dihedral angle between the benzene ring and the chloro-substituted benzene ring is 72.91 (6)°. In the crystal, molecules are linked by C—H...O and C—H...N hydrogen bonds into undulating sheets lying parallel to the bc plane. The crystal is further consolidated by C—H...π interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812024294