A short synthesis of ±-cherylline dimethyl ether

A synthesis of ±-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet-Spengler cyclization.

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Bibliographische Detailangaben
Veröffentlicht in:	Beilstein journal of organic chemistry 2009-12, Vol.5 (1), p.80-80
Hauptverfasser:	Kale, Bhima Y, Shinde, Ananta D, Sonar, Swapnil S, Shingate, Bapurao B, Kumar, Sanjeev, Ghosh, Samir, Venugopal, Soodamani, Shingare, Murlidhar S
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Curtius rearrangement Full Research Paper Michael reaction Pictet–Spengler cyclization radical azidonation
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A synthesis of ±-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet-Spengler cyclization.
ISSN:	1860-5397 1860-5397
DOI:	10.3762/bjoc.5.80