Ethyl 2-[9-(5-bromo-2-hydroxyphenyl)-3,3,6,6-tetramethyl-1,8-dioxo-1,2,3,4,5,6,7,8,9,10-decahydroacridin-10-yl]acetate
In the title compound, C 27 H 32 BrNO 5 , the central 1,4-dihydropyridine ring adopts a shallow sofa conformation (with the C atom bearing the bromophenol ring as the flap), whereas the pendant cyclohexene rings both have twisted-boat conformations. The molecule features an intramolecular O—H...O hy...
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Veröffentlicht in: | IUCrData 2017-04, Vol.2 (4), p.x170573, Article x170573 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, C
27
H
32
BrNO
5
, the central 1,4-dihydropyridine ring adopts a shallow sofa conformation (with the C atom bearing the bromophenol ring as the flap), whereas the pendant cyclohexene rings both have twisted-boat conformations. The molecule features an intramolecular O—H...O hydrogen bond, which closes an
S
(8) ring. In the crystal, molecules are linked by C—H...O interactions, forming
C
(12) chains along the
c
-axis direction. The ethyl acetate grouping is disordered over two sets of sites in a 0.719 (11):0.281 (11) ratio. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314617005739 |