Ethyl 2-[9-(5-bromo-2-hydroxyphenyl)-3,3,6,6-tetramethyl-1,8-dioxo-1,2,3,4,5,6,7,8,9,10-decahydroacridin-10-yl]acetate

In the title compound, C 27 H 32 BrNO 5 , the central 1,4-dihydropyridine ring adopts a shallow sofa conformation (with the C atom bearing the bromophenol ring as the flap), whereas the pendant cyclohexene rings both have twisted-boat conformations. The molecule features an intramolecular O—H...O hy...

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Veröffentlicht in:IUCrData 2017-04, Vol.2 (4), p.x170573, Article x170573
Hauptverfasser: Mohamed, Shaaban K., Dege, Necmi, Akkurt, Mehmet, Allah, Omyma A. Abd, Albayati, Mustafa R.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C 27 H 32 BrNO 5 , the central 1,4-dihydropyridine ring adopts a shallow sofa conformation (with the C atom bearing the bromophenol ring as the flap), whereas the pendant cyclohexene rings both have twisted-boat conformations. The molecule features an intramolecular O—H...O hydrogen bond, which closes an S (8) ring. In the crystal, molecules are linked by C—H...O interactions, forming C (12) chains along the c -axis direction. The ethyl acetate grouping is disordered over two sets of sites in a 0.719 (11):0.281 (11) ratio.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314617005739