Malonates in Cyclocondensation Reactions

The use of malonates such as diethyl malonates 9, (chlorocarbonyl)ketenes 15 and bis(2,4,6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1,3-dinucleophiles to give six-membered heterocycles is described. Further attempts to use malonates such as bis(trimethylsilyl) malonates 1...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2001-03, Vol.6 (4), p.338-352
Hauptverfasser: Stadlbauer, Wolfgang, Badawey, El-Sayed, Hojas, Gerhard, Roschger, Peter, Kappe, Thomas
Format: Artikel
Sprache:eng
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Zusammenfassung:The use of malonates such as diethyl malonates 9, (chlorocarbonyl)ketenes 15 and bis(2,4,6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1,3-dinucleophiles to give six-membered heterocycles is described. Further attempts to use malonates such as bis(trimethylsilyl) malonates 19 and bis(carbamimidoyl) malonates 29 as new cyclocondensation agents are described .
ISSN:1420-3049
1420-3049
DOI:10.3390/60400338