Crystal structure of ( E )-1-(3-benzyl-5-phenyl-1,3-thia-zol-2-yl-idene)-2-[( E )-1,2,3,4-tetra-hydro-naphthalen-1-yl-idene]hydrazin-1-ium bromide

In the title mol-ecular salt, C H N S ·Br , the dihedral angles between the thia-zole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C-H⋯Br and N-H⋯Br hydrogen bonds and are connected into helical chains extending al...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2021-04, Vol.77 (Pt 4), p.420-423
Hauptverfasser: Mohamed, Shaaban K, Elgarhy, Sahar M I, Hassan, Alaa A, Demirtaş, Güneş, Mague, Joel T, Ramli, Youssef
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Sprache:eng
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Zusammenfassung:In the title mol-ecular salt, C H N S ·Br , the dihedral angles between the thia-zole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C-H⋯Br and N-H⋯Br hydrogen bonds and are connected into helical chains extending along the -axis direction by weak, electrostatic S⋯Br inter-actions. A Hirshfeld surface analysis was performed, which showed the dominant role of H⋯H contacts (51.3%).
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989021002863