Crystal structure of ( E )-1-(3-benzyl-5-phenyl-1,3-thia-zol-2-yl-idene)-2-[( E )-1,2,3,4-tetra-hydro-naphthalen-1-yl-idene]hydrazin-1-ium bromide
In the title mol-ecular salt, C H N S ·Br , the dihedral angles between the thia-zole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C-H⋯Br and N-H⋯Br hydrogen bonds and are connected into helical chains extending al...
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Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2021-04, Vol.77 (Pt 4), p.420-423 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title mol-ecular salt, C
H
N
S
·Br
, the dihedral angles between the thia-zole ring and its attached phenyl and benzoyl rings are 54.81 (7) and 85.51 (7)°, respectively. In the crystal, ion pairs are linked by C-H⋯Br and N-H⋯Br hydrogen bonds and are connected into helical chains extending along the
-axis direction by weak, electrostatic S⋯Br
inter-actions. A Hirshfeld surface analysis was performed, which showed the dominant role of H⋯H contacts (51.3%). |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989021002863 |