A Sodium Chloride Modification of SnO2 Electron Transport Layers to Enhance the Performance of Perovskite Solar Cells

A sodium chloride modification was applied where different amounts of sodium chloride was physically blended in a tin oxide colloid solution to passivate the interface between the electron transport layer (ETL) and perovskite layer and improve the performance of perovskite solar cells. Sodium chlori...

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Veröffentlicht in:ACS omega 2021-07, Vol.6 (28), p.17880-17889
Hauptverfasser: Lin, Ching Chang, Murakami, Takurou N, Chikamatsu, Masayuki, Bessho, Takeru, Furue, Miwako, Segawa, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:A sodium chloride modification was applied where different amounts of sodium chloride was physically blended in a tin oxide colloid solution to passivate the interface between the electron transport layer (ETL) and perovskite layer and improve the performance of perovskite solar cells. Sodium chloride-modified tin oxide was utilized as the electron transport material to fabricate perovskite solar cells. It was found that sodium chloride-modified tin oxide as an ETL could considerably enhance the performance of the device compared to pristine tin oxide. The power conversion efficiency of the perovskite solar cell displayed 8.8% remarkable improvement from 18.7 ± 0.4% to 20.3 ± 0.3% on average and 9.5% improvement from 18.9 to 20.7% in champion devices because of the considerable enhancement of the fill factor when 25 mM sodium chloride-modified tin oxide as the ETL was used in comparison with pristine tin oxide.
ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.1c01286