(Ethylenediamine-κ 2 N , N )bis[2-(pyridin-2-yl-κ N )-1,3-imidazol-1-ido-κ N 1 ]cobalt(III) nitrate monohydrate
In the title compound, [Co(C 8 H 6 N 3 ) 2 (C 2 H 8 N 2 )]NO 3 ·H 2 O, the Co III ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (9), p.m1155-m1155 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, [Co(C
8
H
6
N
3
)
2
(C
2
H
8
N
2
)]NO
3
·H
2
O, the Co
III
ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812032692 |