Effect of gas injection on cavitation-assisted plasma treatment efficiency of wastewater

•Investigation on gas injection during ACAP process is conducted.•Argon provides a better efficiency of Rhodamine B degradation compared to air.•Hydrogen and oxygen-containing radicals are generated in larger amount during argon injection.•Argon dissolves in water that lowers breakdown voltage and improves cavitation treatment. Underwater plasma has been long recognized as a “green” alternative to conventional chemicals in the wastewater treatment processes. However, practical application of underwater plasma is still challenging due to insufficient treatment performance. Recently, we proposed a novel process named ACAP utilizing acoustic cavitation in order to stabilize the plasma generation and to enlarge the plasma processing region. This work continues our investigation regarding the ACAP treatment process focusing on effects of gas injection. Experiments were performed using an ultrasonic installation equipped with a specially designed sonotrode (Diam. 48 mm) operated at a frequency of 20 kHz and acoustic power of 120 W. The results revealed that the degradation efficiency of Rhodamine B, which was used as a model wastewater pollutant, remains almost unchangeable in the case of air injection, but it is doubled when argon is injected into the ACAP reactor. It was found that the argon injection enhances the degradation efficiency significantly even without ultrasound irradiation. Results of additional measurements suggest that the effect of argon is attributed to its ability to yield high temperature during cavitation, comparatively good solubility in water and a better ability to reduce the breakdown voltage in water compared to the air case.