A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts

A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts

The reaction of pyridine with cyanuric chloride was studied under microwave activation as well as in the presence of silver nitrate. The product of hydrolysis containing two pyridinium rings and chloride anion was isolated. The structures of these anion exchanger salts with chloride, nitrate and per...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2023-02, Vol.28 (4), p.1941
Hauptverfasser: Zakharov, Valery N, Lemport, Pavel S, Chernyshev, Vladimir V, Tafeenko, Victor A, Yatsenko, Alexandr V, Ustynyuk, Yuri A, Dunaev, Sergey F, Nenajdenko, Valentine G, Aslanov, Leonid A
Format: Artikel
Sprache:eng
Schlagworte:
1,3,5-triazine
anion exchanger
Anion exchanging
Anions
Anions - chemistry
Aqueous solutions
Chloride
Chlorides
Chlorides - chemistry
crystal structure
Crystals
DFT
Hydrolysis
Ions
Nitrates
Nitrates - chemistry
NMR
Nuclear power plants
Nuclear reactors
precipitation of perrhenate
Pyridine
s-triazines
Salts
Silver
Silver nitrate
Structure
Triazine
Triazines - chemistry
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Zusammenfassung:The reaction of pyridine with cyanuric chloride was studied under microwave activation as well as in the presence of silver nitrate. The product of hydrolysis containing two pyridinium rings and chloride anion was isolated. The structures of these anion exchanger salts with chloride, nitrate and perrhenate anions are discussed.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules28041941