Recent synthetic studies leading to structural revisions of marine natural products

Because of the highly unique structures of marine natural products, there are many examples of structures that were originally proposed based on spectral analyses but later proven incorrect. In many cases, the total syntheses of the originally proposed structures of marine natural products has confi...

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Veröffentlicht in:	Marine drugs 2009-07, Vol.7 (3), p.314-330
1. Verfasser:	Usami, Yoshihide
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals Biological Products - chemical synthesis Biological Products - chemistry Drug Discovery - methods Marine Biology - methods marine natural product Oceans and Seas Review Spectrum Analysis - methods Stereoisomerism stereoselective structural revision synthesis
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Beschreibung
Zusammenfassung:	Because of the highly unique structures of marine natural products, there are many examples of structures that were originally proposed based on spectral analyses but later proven incorrect. In many cases, the total syntheses of the originally proposed structures of marine natural products has confirmed their incorrectness and the subsequent total syntheses of the newly proposed structures proved the revised structures. This review will show such cases appearing after 2005 and demonstrate how the true structures were elucidated.
ISSN:	1660-3397 1660-3397
DOI:	10.3390/md7030314