Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds

Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds

Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other appl...

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Veröffentlicht in:Beilstein journal of organic chemistry 2008-10, Vol.4 (1), p.36-36
Hauptverfasser: Osipov, Maksim, Chu, Qianli, Geib, Steven J, Curran, Dennis P, Weber, Stephen G
Format: Artikel
Sprache:eng
Schlagworte:
(perfluoroalkyl)alkyl aryl ethers
calixarene
Chemistry
fluorous
Full Research Paper
hydrofluoroethers
organofluorine
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Zusammenfassung:Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other applications.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.4.36