Chlorido(dimethyl sulfoxide-κ O )triphenyltin(IV)
In the title compound, [Sn(C6H5)3Cl(C2H6OS)], the SnIV atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide molecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent molecules are linked through intermolecular C—H...Cl hydrogen bonds, we...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-12, Vol.65 (12), p.m1602-m1603 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, [Sn(C6H5)3Cl(C2H6OS)], the SnIV atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide molecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent molecules are linked through intermolecular C—H...Cl hydrogen bonds, weak C—H...π interactions and π–π interactions [centroid–centroid distance = 3.934 (3) Å. An intramolecular C—H...π interaction is also observed. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809048090 |