Effect of the type and time of stirring in the catalytic activity of rutheniumporphyrin

In this work, the complex (carbonyl)[tetrakis(5,10,15,20-ortho-bromo-phenyl)porphyrin]ruthenium(II) was synthesized and its behavior as catalyst was investigated in the oxidation of cyclohexane by iodosylbenzene. The influence of the stirring (mechanical and ultra-sound) of the system was investigat...

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Veröffentlicht in:Eclética química 2018-05, Vol.27 (2)
Hauptverfasser: Christian Alexander Guimarães, Margarida de Moraes
Format: Artikel
Sprache:eng ; por
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Zusammenfassung:In this work, the complex (carbonyl)[tetrakis(5,10,15,20-ortho-bromo-phenyl)porphyrin]ruthenium(II) was synthesized and its behavior as catalyst was investigated in the oxidation of cyclohexane by iodosylbenzene. The influence of the stirring (mechanical and ultra-sound) of the system was investigated and the results demonstrated good efficiency, selectivity and regeneration of the catalyst, when a mixed system of stirring was used.
ISSN:1678-4618
DOI:10.1590/S0100-46702002000200030