Effect of the type and time of stirring in the catalytic activity of rutheniumporphyrin
In this work, the complex (carbonyl)[tetrakis(5,10,15,20-ortho-bromo-phenyl)porphyrin]ruthenium(II) was synthesized and its behavior as catalyst was investigated in the oxidation of cyclohexane by iodosylbenzene. The influence of the stirring (mechanical and ultra-sound) of the system was investigat...
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Veröffentlicht in: | Eclética química 2018-05, Vol.27 (2) |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng ; por |
Online-Zugang: | Volltext |
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Zusammenfassung: | In this work, the complex (carbonyl)[tetrakis(5,10,15,20-ortho-bromo-phenyl)porphyrin]ruthenium(II) was synthesized and its behavior as catalyst was investigated in the oxidation of cyclohexane by iodosylbenzene. The influence of the stirring (mechanical and ultra-sound) of the system was investigated and the results demonstrated good efficiency, selectivity and regeneration of the catalyst, when a mixed system of stirring was used. |
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ISSN: | 1678-4618 |
DOI: | 10.1590/S0100-46702002000200030 |