Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N′,N′-tetramethylethylenediamino)tetracopper(I)

A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four coppe...

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Veröffentlicht in:MolBank 2024-06, Vol.2024 (2), p.M1832
Hauptverfasser: Ray, Matthew J., Saviantoni, Maria Laura, Slawin, Alexandra M. Z., Cordes, David B., Kilian, Petr
Format: Artikel
Sprache:eng
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Zusammenfassung:A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1832