Bis(N-tert-butylacetamido)(dimethylamido)(chloro)titanium

Bis(N-tert-butylacetamido)(dimethylamido)(chloro)titanium

The titanium amidate compound bis(N-tert-butylacetamido)(dimethylamido)(chloro)titanium was synthesized by the protonolysis of tris(dimethylamido)(chloro)titanium and structurally characterized by 1H and 13C NMR spectroscopy as well as X-ray diffraction. The compound does not appear to react cleanly...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:MolBank 2024-03, Vol.2024 (1), p.M1786
Hauptverfasser: Seth, Dennis M., Waterman, Rory
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
amidate
Butyllithium
Catalysis
Computer centers
crystal
Crystals
Hydrocarbons
Ligands
Nitrogen
NMR spectroscopy
Solvents
Titanium
Titanium compounds
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The titanium amidate compound bis(N-tert-butylacetamido)(dimethylamido)(chloro)titanium was synthesized by the protonolysis of tris(dimethylamido)(chloro)titanium and structurally characterized by 1H and 13C NMR spectroscopy as well as X-ray diffraction. The compound does not appear to react cleanly nor readily with routine alkylating agents such as sec-butyllithium, benzyl potassium, or trimethylsilyl methyllithium.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1786