Crystal structure of ( Z )-3-(4-methoxybenzylidene)-2,3-dihydrobenzo[ b ][1,4]thiazepin-4(5 H )-one
In the title compound, C 17 H 15 NO 2 S, the two C atoms linking the S and carbonyl C atoms of the seven-membered thiazepine ring are disordered over two sites, with occupancies of 0.511 (4) and 0.489 (4); both disorder components adopt distorted twist-boat conformations. In the crystal, N—H...O and...
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Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-01, Vol.71 (1), p.o21-o22 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, C
17
H
15
NO
2
S, the two C atoms linking the S and carbonyl C atoms of the seven-membered thiazepine ring are disordered over two sites, with occupancies of 0.511 (4) and 0.489 (4); both disorder components adopt distorted twist-boat conformations. In the crystal, N—H...O and C—H...O hydrogen bonds link inverted-related molecules into dimers, incorporating
R
1
2
(6) and
R
2
2
(8) ring motifs; the acceptor carbonyl O atom is bifurcated. These dimers are further linked by C—H...O hydrogen bonds, forming supramolecular tapes running along the
a
axis. |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989014026267 |