An Exfoliated Graphite-Based Bisphenol A Electrochemical Sensor

The use of an exfoliated graphite (EG) electrode in the square wave voltammetric detection of bisphenol A (a model phenolic pollutant) in water, whereby the phenolic electrode fouling challenge is mitigated, is described. The oxidation peak of BPA was observed at about 0.45 V in phosphate buffer sol...

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Veröffentlicht in:Sensors (Basel, Switzerland) Switzerland), 2012-09, Vol.12 (9), p.11601-11611
Hauptverfasser: Ndlovu, Thabile, Arotiba, Omotayo A., Sampath, Srinivasan, Krause, Rui W., Mamba, Bhekie B.
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Sprache:eng
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Zusammenfassung:The use of an exfoliated graphite (EG) electrode in the square wave voltammetric detection of bisphenol A (a model phenolic pollutant) in water, whereby the phenolic electrode fouling challenge is mitigated, is described. The oxidation peak of BPA was observed at about 0.45 V in phosphate buffer solution at pH 10. The current response exhibited a linear relationship with the concentration over a range from 1.56 µM–50 µM. The detection limit was calculated to be 0.76 µM. The EG electrode surface was renewed after each measurement with excellent reproducibility. A real sample application was also investigated.
ISSN:1424-8220
1424-8220
DOI:10.3390/s120911601