Surface Texture of Microcrystalline Tunnel-Structured Manganese(IV) Oxides: Nitrogen Sorptiometry and Electron Microscopy Studies

Three different modifications of manganese(IV) oxide, viz. cryptomelane, nsutite and todorokite-like, were synthesized by hydrothermal methods. The bulk chemical composition, phase composition, crystalline structure and particle morphology of the resulting materials were determined by thermogravimet...

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Veröffentlicht in:Adsorption science & technology 2002-09, Vol.20 (7), p.619-632
Hauptverfasser: Ali, A.A., Al-Sagheer, F.A., Zaki, M.I.
Format: Artikel
Sprache:eng
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Zusammenfassung:Three different modifications of manganese(IV) oxide, viz. cryptomelane, nsutite and todorokite-like, were synthesized by hydrothermal methods. The bulk chemical composition, phase composition, crystalline structure and particle morphology of the resulting materials were determined by thermogravimetry, atomic absorption spectroscopy, X-ray diffractometry, infrared spectroscopy and scanning electron microscopy. The surface chemical composition, texture and structure were assessed using X-ray photoelectron microscopy, nitrogen sorptiometry and high-resolution electron microscopy. The results highlighted the hydrothermal conditions under which such tunnel-structured modifications of manganese(IV) oxide can be successfully synthesized. Moreover, they revealed that (i) the bulk was microcrystalline, (ii) the crystallites were either fibrils (cryptomelane and nsutite) or rod-like (todorokite) with low-index exposed facets, (iii) the surface chemical composition mostly reflected that of the bulk and (iv) the surface texture was linked with high specific areas, slit-shaped mesopores associated with particle interstices and micropores which allowed surface accessibility to the bulk tunnels of the test oxides. The application of such test oxides as shape-selective oxidation catalysts appears worthy of investigation.
ISSN:0263-6174
2048-4038
DOI:10.1260/02636170260504314