Incidental Polymorphism, Non-Isomorphic and Isomorphic Substitution in Calcium-Valine Coordination Polymers
Five coordination polymers with the stoichiometry CaX2(valine)2(H2O)2 (X = Cl, Br) were obtained from the corresponding calcium halides and either racemic and enantiopure valine. In all cases the zwitterionic amino acid is exclusively O coordinated and the halides act as counteranions for the result...
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Veröffentlicht in: | Crystals (Basel) 2015-06, Vol.5 (2), p.261-272 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Five coordination polymers with the stoichiometry CaX2(valine)2(H2O)2 (X = Cl, Br) were obtained from the corresponding calcium halides and either racemic and enantiopure valine. In all cases the zwitterionic amino acid is exclusively O coordinated and the halides act as counteranions for the resulting one-dimensional cationic chains. The enantiopure chloride shows dimorphism; both forms differ in connectivity from the bromide. In contrast to this structural variability for L-valine, the derivatives of the racemic amino acid are isomorphous. |
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ISSN: | 2073-4352 2073-4352 |
DOI: | 10.3390/cryst5020261 |