Thermodynamic analysis of copper(I) sulfide chlorination by calcium chloride in the presence of oxygen
This paper presents a thermodynamic analysis of possible, but insufficiently studied, chemical reactions occurring during the chlorination of copper(I) sulfide by calcium chloride in the presence of oxygen. It formed the basis for assessing the probability and priority of their occurrence. Phase sta...
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Veröffentlicht in: | Journal of the Serbian Chemical Society 1999, Vol.64 (5-6), p.365-374 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | This paper presents a thermodynamic analysis of possible, but insufficiently
studied, chemical reactions occurring during the chlorination of copper(I)
sulfide by calcium chloride in the presence of oxygen. It formed the basis
for assessing the probability and priority of their occurrence. Phase
stability diagrams have been plotted for the Cu-S-O-Cl system in the
coordinates log p(S2)-log p(O2)-log p(Cl2) in the temperature range from 473
to 773 K.
nema |
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ISSN: | 0352-5139 1820-7421 |
DOI: | 10.2298/JSC9906365V |