Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Metal-organic frameworks [M (2-I-bdc) bpe] (M = Zn(II) ( ), Co(II) ( ), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sor...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2022-02, Vol.27 (4), p.1305
Hauptverfasser: Zaguzin, Alexander S, Sukhikh, Taisiya S, Sakhapov, Ilyas F, Fedin, Vladimir P, Sokolov, Maxim N, Adonin, Sergey A
Format: Artikel
Sprache:eng
Schlagworte:
carboxylates
Cobalt
Coordination polymers
Ethane
Experiments
Hydrocarbons
Iodine
Ligands
Metal-organic frameworks
Polymers
Selectivity
Sorption
Vapor phases
Zinc
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Zusammenfassung:Metal-organic frameworks [M (2-I-bdc) bpe] (M = Zn(II) ( ), Co(II) ( ), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules27041305