Self-diffusion of water molecules after contact with silicon-containing compounds

Influence of crystalline and amorphous silica on the diffusion coefficients of water molecules according to the experimental data on quasi-elastic scattering of slow neutrons is quantified. It was established that after the contact of silicon-containing compounds of natural origin chalcedony and spo...

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Veröffentlicht in:I͡A︡derna fizyka ta enerhetyka 2018-06, Vol.19 (2), p.131-135
Hauptverfasser: Slisenko, V.I., Vasylkevych, O.A., Mazina, N.I., Karmazina, T.V.
Format: Artikel
Sprache:eng ; ukr
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Zusammenfassung:Influence of crystalline and amorphous silica on the diffusion coefficients of water molecules according to the experimental data on quasi-elastic scattering of slow neutrons is quantified. It was established that after the contact of silicon-containing compounds of natural origin chalcedony and spongolit with water, the mechanisms of its self-diffusion are significantly changed: self-diffusion is carried out only by the mechanism of continuous diffusion; the magnitude of the total self-diffusion coefficient of water molecules decreases and there is no contribution from the activation mechanism of self-diffusion by at least 24 hours after separation of the solid phase from the liquid. The pyrogenic amorphous silica has relatively little effect on the diffusion of water molecules.
ISSN:1818-331X
2074-0565
DOI:10.15407/jnpae2018.02.131