( S p )-1-Diphenylphosphanyl-2-{( S )-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene
The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal-pyramidal conformation. There is a short intramolecular C-H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved i...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-12, Vol.64 (12), p.m1585-m1585 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal-pyramidal conformation. There is a short intramolecular C-H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved in an intramolecular O-H...πphenyl interaction. The crystal packing shows five very weak intermolecular C-H...π contacts, with H...Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclopentadienyl ring). |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536808038294 |