( S p )-1-Diphenylphosphanyl-2-{( S )-[2-(diphenylphosphanyl)phenyl]hydroxymethyl}ferrocene

The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal-pyramidal conformation. There is a short intramolecular C-H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved i...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-12, Vol.64 (12), p.m1585-m1585
Hauptverfasser: Bats, Jan W., Doppiu, Angelino, Rivas Nass, Andreas, Hashmi, A. Stephen K.
Format: Artikel
Sprache:eng
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Zusammenfassung:The absolute configuration of the title compound, [Fe(C5H5)(C36H29OP2)], is Sp at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal-pyramidal conformation. There is a short intramolecular C-H...P contact with an H...P distance of 2.56 Å. The hydroxy group is involved in an intramolecular O-H...πphenyl interaction. The crystal packing shows five very weak intermolecular C-H...π contacts, with H...Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclopentadienyl ring).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808038294