A study on the coordination of cyclohexanocucurbit[6]uril with copper, zinc, and magnesium ions

A study on the coordination of cyclohexanocucurbit[6]uril with copper, zinc, and magnesium ions

Herein, we report the supramolecular complexes of cyclohexanocucurbit[6]uril (CyH Q[6]) with Cu(ClO , Zn(ClO , and Mg(ClO in formic acid solution. The crystal structure was determined using single crystal X-ray diffraction. The analysis results showed that CyH Q [6] formed a one-dimensional supramol...

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Veröffentlicht in:Green processing and synthesis 2021-12, Vol.10 (1), p.835-841
Hauptverfasser: Zheng, Jun, Zhang, Lin, Yang, Xinan, Jin, Yanmei, Gao, Jie, Ma, Peihua
Format: Artikel
Sprache:eng
Schlagworte:
Copper
Crystal structure
Crystals
CyH
cyh6q
Dipole interactions
Formic acid
ion–dipole interaction
Magnesium
Magnesium perchlorates
Metal ions
Single crystals
supramolecular complexes
X-ray diffraction
Zinc
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Zusammenfassung:Herein, we report the supramolecular complexes of cyclohexanocucurbit[6]uril (CyH Q[6]) with Cu(ClO , Zn(ClO , and Mg(ClO in formic acid solution. The crystal structure was determined using single crystal X-ray diffraction. The analysis results showed that CyH Q [6] formed a one-dimensional supramolecular chain with Cu(ClO and formed a supramolecular assembly with a mixture ratio of 2:3 with Zn(ClO and Mg(ClO . In this system, induced CyH Q[6] and metal ions to form supramolecular complexes through ion–dipole interactions.
ISSN:2191-9550
2191-9542
2191-9550
DOI:10.1515/gps-2021-0074