Dynamically probing ultracold lattice gases via Rydberg molecules

We show that the excitation of long-range Rydberg molecules in a three-dimensional optical lattice can be used as a position- and time-sensitive probe for doubly occupied sites in the system. To this end, we detect the ions which are continuously generated by the decay of the formed Rydberg molecules. While a superfluid gas shows molecule formation for all parameters, a Mott insulator with n = 1 filling reveals a strong suppression of the number of formed molecules. In the limit of weak probing, the technique can be used to probe the superfluid to Mott-insulator transition in real-time. Our method can be extended to higher fillings and has various applications for the real-time diagnosis and manipulation of ultracold lattice gases.