Stability of Palladium(II) beta-cyclodextrin nanocomposite in aqueous media and its catalytic activity in Homocoupling of Arylboronic acid
Palladium(II) beta-Cyclodextrin (Pd(II)-b-CD) nanocomposites are water-soluble compounds which can be of great importance for performing palladium-catalyzed reactions in aqueous media. The stability of water-soluble Pd(II)-b-CD nanocomposites in water were examined and was found that this...
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Veröffentlicht in: | Zanco journal of pure and applied sciences 2020-09, Vol.32 (4) |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Palladium(II) beta-Cyclodextrin (Pd(II)-b-CD) nanocomposites are water-soluble compounds which can be of great importance for performing palladium-catalyzed reactions in aqueous media. The stability of water-soluble Pd(II)-b-CD nanocomposites in water were examined and was found that this nanocomposit is losing its stability in water significantly with time in the time interval of 0 to 200 minutes. In addition, the Pd(II)-b-CD nanocomposite was used as a catalyst for Aerobic homocoupling of arylboronic acid (ArBA) in water. However, the results showed that the catalytic activity of same prepared Pd(II)-b-CD nanocomposite stock solution in water for homocoupling reaction of ArBA decreases with time significantly. The Stability of the Pd(II)-b-CD nanocomposite was monitored using Ultra Violet- Visible (UV-Vis) spectroscopy. used to monitor the catalyst stability |
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ISSN: | 2218-0230 2412-3986 |