RAFT polymerization-induced self-assembly of poly(ionic liquids) in ethanol

Poly(ionic liquids) (PILs) exhibit better durability, processability, and mechanical stability than ionic liquids. PIL self-assembly in green solvents is a well-established strategy for preparing polyelectrolytes. Reversible addition-fragmentation chain transfer (RAFT) polymerization-induced self-assembly (PISA) has proven to be the most controllable method for synthesizing polyelectrolytes. However, there have been few reports on preparing high-order morphology PILs by RAFT-PISA. A new type of ionic monomer, 1-butyl-3-(4-vinylbenzyl)imidazolium hexafluorophosphate ([BVBIm][PF ]), was prepared from substitution reaction and ion exchange reaction of 1-butylimidazole and 4-vinylbenzyl chloride. Herein, various morphologies, including spheres, worms, and vesicles, were easily obtained via RAFT ethanolic dispersion polymerization using poly( -dimethylacrylamide) (PDMA ) as the macromolecular chain transfer agent and [BVBIm][PF ] as the monomer. Dispersion polymerization kinetic experiments, dynamic light scattering, transmission electron microscopy, and differential scanning calorimetry were used to investigate the PDMA -P([BVBIm][PF ]) block nanoparticles. This efficient RAFT-PISA method for preparing functionalized PIL nano-objects with controlled morphologies represents significant progress in this field.