Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II)
In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are dis...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-10, Vol.66 (Pt 10), p.m1236-m1236 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π-π inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances = 3.8821 (9) and 3.9502 (10) Å, respectively] stabilize the structure. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810035531 |