Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II)

In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are dis...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-10, Vol.66 (Pt 10), p.m1236-m1236
Hauptverfasser: Akbarzadeh Torbati, Niloufar, Rezvani, Ali Reza, Safari, Nasser, Amani, Vahid, Khavasi, Hamid Reza
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Sprache:eng
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Zusammenfassung:In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π-π inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances = 3.8821 (9) and 3.9502 (10) Å, respectively] stabilize the structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810035531