Crystal structure of bromidobis(naphthalen-1-yl)antimony(III)

Crystal structure of bromidobis(naphthalen-1-yl)antimony(III)

In the title compound, [SbBr(C 10 H 7 ) 2 ], the Sb III atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intramolecular C—H...Br hydrogen bond forms an S (5) ring motif. In the crystal, weak C—H....

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-10, Vol.70 (10), p.m351-m351
Hauptverfasser: Shawkataly, Omar bin, Hussien Abdelnasir, Hafiz Malik, Rosli, Mohd Mustaqim
Format: Artikel
Sprache:eng
Schlagworte:
crystal structure
hydrogen bonding
organoantimony(III) compounds
stibine
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Beschreibung
Zusammenfassung:In the title compound, [SbBr(C 10 H 7 ) 2 ], the Sb III atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intramolecular C—H...Br hydrogen bond forms an S (5) ring motif. In the crystal, weak C—H...Br interactions link the molecules into helical chains along the b- axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536814020066