(η 5 -Pentamethylcyclopentadienyl)(η 6 -toluene)ruthenium(II) hexafluoridophosphate

In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ri...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-10, Vol.66 (10), p.m1264-m1264
Hauptverfasser: O, Wylie W. N., Lough, Alan J., Morris, Robert H.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C—H...F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810036299