(η 5 -Pentamethylcyclopentadienyl)(η 6 -toluene)ruthenium(II) hexafluoridophosphate
In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ri...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-10, Vol.66 (10), p.m1264-m1264 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C—H...F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810036299 |