Solidification Morphology and Bifurcation Predictions with the Maximum Entropy Production Rate Model
The use of the principle of maximum entropy generation per unit volume is a new approach in materials science that has implications for understanding the morphological evolution during solid–liquid interface growth, including bifurcations with or without diffuseness. A review based on a pre-publicat...
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Veröffentlicht in: | Entropy (Basel, Switzerland) Switzerland), 2020-01, Vol.22 (1), p.40 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The use of the principle of maximum entropy generation per unit volume is a new approach in materials science that has implications for understanding the morphological evolution during solid–liquid interface growth, including bifurcations with or without diffuseness. A review based on a pre-publication arXiv preprint is first presented. A detailed comparison with experimental observations indicates that the Maximum Entropy Production Rate-density model (MEPR) can correctly predict bifurcations for dilute alloys during solidification. The model predicts a critical diffuseness of the interface at which a plane-front or any other form of diffuse interface will become unstable. A further confidence test for the model is offered in this article by comparing the predicted liquid diffusion coefficients to those obtained experimentally. A comparison of the experimentally determined solute diffusion constant in dilute binary Pb–Sn alloys with those predicted by the various solidification instability models (1953–2011) is additionally discussed. A good predictability is noted for the MEPR model when the interface diffuseness is small. In comparison, the more traditional interface break-down models have low predictiveness. |
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ISSN: | 1099-4300 1099-4300 |
DOI: | 10.3390/e22010040 |