Collinear laser spectroscopy of Ca^{+}: Solving the field-shift puzzle of the 4s^{2}S_{1/2}→4p^{2}P_{1/2,3/2} transitions

High-precision quasisimultaneous collinear/anticollinear laser spectroscopy was used to measure the 4s^{2}S_{1/2}→4p^{2}P_{1/2} (D1) and the 4s^{2}S_{1/2}→4p^{2}P_{3/2} (D2) as well as the three 3d→4p transitions in the naturally abundant Ca^{+} isotopes. Thereby, accuracies of approximately 100kHz...

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Veröffentlicht in:Physical review research 2020-12, Vol.2 (4), p.043351
Hauptverfasser: Patrick Müller, Kristian König, Phillip Imgram, Jörg Krämer, Wilfried Nörtershäuser
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Sprache:eng
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Zusammenfassung:High-precision quasisimultaneous collinear/anticollinear laser spectroscopy was used to measure the 4s^{2}S_{1/2}→4p^{2}P_{1/2} (D1) and the 4s^{2}S_{1/2}→4p^{2}P_{3/2} (D2) as well as the three 3d→4p transitions in the naturally abundant Ca^{+} isotopes. Thereby, accuracies of approximately 100kHz were achieved, which enabled an accurate determination of the field-shift ratio in the D2 and D1 lines through a King-plot analysis. Our value of F_{D2}/F_{D1}=1.0010(23) is in excellent agreement with current theoretical predictions, while former experimental results from ion-trap measurements showed a 3σ to 6σ deviation from theory introducing the so-called Ca^{+} field-shift puzzle. A successful check of consistency was made by combining the measurements of the D1 and D2 lines with those of the 3d→4p transitions and precise literature values for the 4s→3d and 3d^{2}D_{3/2}→3d^{2}D_{5/2} transitions. Failing for the previous ion-trap measurements, the check of consistency strongly indicates that our results constitute a solution to this puzzle, supporting the results of atomic theory.
ISSN:2643-1564
DOI:10.1103/PhysRevResearch.2.043351