Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation

Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation

The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t -butanol reaction system.

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Bibliographische Detailangaben
Veröffentlicht in:BMC chemistry 2017-12, Vol.11 (1), p.138-9, Article 138
Hauptverfasser: Wang, Qing-yao, Fang, Jia-qi, Deng, Lu-lu, Hao, Xiao-jiang, Mu, Shu-zhen
Format: Artikel
Sprache:eng
Schlagworte:
Alkali metal
Alkali metals
Aryl halides
Butanol
Chemical research
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dehalogenation
Derivatives
Halogenated dibenzocyclooctadiene lignans
Lignans
Methods
Organic and Medicinal Chemistry
Oxidation-reduction reactions
Polyphenols
Properties
Reduction (metal working)
Regioselective demethoxylation
Regioselectivity
Research Article
Structure-activity relationships (Biochemistry)
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Zusammenfassung:The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t -butanol reaction system.
ISSN:1752-153X
1752-153X
2661-801X
DOI:10.1186/s13065-017-0368-z