5-(4-Bromo-anilinomethyl-ene)-2,2-dimethyl-1,3-dioxane-4,6-dione

In the title compound, C(13)H(12)BrNO(4), the dihedral angles between the amino-methyl-ene group and the dioxane ring and between the benzyl ring and the amino-methyl-ene unit are 7.96 (4) and 12.15 (4)°, respectively. The dioxane ring shows a half-boat conformation, in which the C atom between the...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-09, Vol.65 (Pt 10), p.o2458-o2458
Hauptverfasser: Shi, Jian-You, Yang, Jin-Cheng, Yang, Jin-Liang
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C(13)H(12)BrNO(4), the dihedral angles between the amino-methyl-ene group and the dioxane ring and between the benzyl ring and the amino-methyl-ene unit are 7.96 (4) and 12.15 (4)°, respectively. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.460 (8) Å out of the plane through the remaining ring atoms. An intra-molecular N-H⋯O hydrogen bond may stabilize the planar conformation of the mol-ecule. An inter-molecular C-H⋯O inter-action is also present.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809035776