Two new zinc(ii) coordination complexes constructed by phenanthroline derivate: Synthesis and structure

Two new zinc(ii) coordination complexes constructed by phenanthroline derivate: Synthesis and structure

Two new Zn( ) coordination complexes [Zn(L)(dna)(H O)] ( ) and [Zn(L)(glu)] ·H O ( ) (L = 2-(4-fluorophenyl)-1 -imidazo[4,5- ][1,10]phenanthroline, H dna = 3,5-dinitrosalicylic acid, H glu = glutaric acid) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, el...

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Veröffentlicht in:Main group metal chemistry 2023-04, Vol.46 (1), p.m248-m249
Hauptverfasser: Feng, Jingdong, Su, Beihao, Yi, Xinxin, Kong, Zhiguo, Chang, Limin
Format: Artikel
Sprache:eng
Schlagworte:
3,5-dinitrosalicylic acid
acid
Anions
Chelation
coordination complex
Coordination compounds
glutaric
glutaric2− acid
Infrared analysis
Ligands
Single crystals
Zinc coordination
zn(ii)
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Zusammenfassung:Two new Zn( ) coordination complexes [Zn(L)(dna)(H O)] ( ) and [Zn(L)(glu)] ·H O ( ) (L = 2-(4-fluorophenyl)-1 -imidazo[4,5- ][1,10]phenanthroline, H dna = 3,5-dinitrosalicylic acid, H glu = glutaric acid) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, elemental analysis, fluorescence spectrum, and infrared spectroscopy. For complex , the dna anion adopts chelating bidentate mode to coordinate with one Zn( ) atom and stacking interactions are formed between the L ligands. For complex , glu anions connect Zn( ) atoms to form a wavy two-dimensional layer, and the L ligands are attached on two sides of the two-dimensional layer.
ISSN:2191-0219
0792-1241
2191-0219
DOI:10.1515/mgmc-2022-8042